Ethyltrichlorosilane

CAS Number

115-21-9

Molecular Formula

C2H5Cl3Si

Also known as:

ETCS; Trichloroethylsilane; Ethyl silicon trichloride; Trichloro(ethyl)silane.

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Product Description

Product Introduction

Ethyltrichlorosilane (CAS 115-21-9), also known as ETCS, is an organometallic compound belonging to the organohalosilane family. It is a colorless, clear liquid with a pungent, suffocating odor due to its reaction with moisture to release hydrogen chloride (HCl). ETCS is a fundamental building block in the silicones industry, primarily utilized for introducing ethyl functionality into silicone polymers and as a surface treatment agent to impart hydrophobic characteristics to various substrates.


Product Selling Points

1. High Trichlorosilane Reactivity

  • Advantage: Readily undergoes hydrolysis and condensation to form stable siloxane networks.

  • Benefit: Efficient Synthesis: Accelerates the production of high-performance silicone resins, saving energy and reducing cycle times.

2. Strong Hydrophobic Properties

  • Advantage: Effectively introduces ethyl groups into siloxane chains or onto surfaces.

  • Benefit: Superior Protection: Enhances the water-repellency of masonry, textiles, and coatings, significantly extending the life of treated materials.

3. Strict Purity Control (≥ 99.0%)

  • Advantage: Low levels of impurities like silicon tetrachloride and branched isomers.

  • Benefit: Consistent Quality: Ensures predictable reaction kinetics and high-quality end-products with excellent mechanical and thermal stability.


Applications

Silicone Resin Synthesis

Used as a primary raw material for manufacturing silicone resins where ethyl groups are required to modify the flexibility and heat resistance of the polymer.

Waterproofing & Surface Treatment

Applied in the formulation of water-repellent agents for masonry, ceramics, and textiles to provide a durable hydrophobic barrier.

Chemical Intermediates

Serves as a vital intermediate for the production of ethyl-based silicates and other specialized organosilicon derivatives.

Laboratory Reagent

Employed in organic synthesis for the introduction of ethylsilyl groups in specialized chemical research and pharmaceutical intermediates.


Packaging & Storage

  • Packaging: 200kg UN-certified steel drums or ISO tanks.

  • Storage: Store in a cool, dry, and well-ventilated warehouse. Crucial: Keep away from moisture, heat, and open flames. Containers must be hermetically sealed with nitrogen padding to prevent hydrolysis.


Matching Materials

  • Methyltrichlorosilane (CAS 75-79-6) —— Co-monomer for silicone resin modification

  • Dimethyldichlorosilane (CAS 75-78-5) —— Chain extender in silicone polymers

  • Phenyltrichlorosilane (CAS 98-13-5) —— Enhancer for thermal stability in resins

  • Trimethylchlorosilane (CAS 75-77-4) —— End-capping agent for chain termination

  • Ethanol (CAS 64-17-5) —— Reagent for ethoxysilane synthesis

  • Methanol (CAS 67-56-1) —— Reagent for methoxysilane synthesis

  • Toluene (CAS 108-88-3) —— Reaction solvent and diluent

  • Platinum Catalyst (CAS 12607-70-4) —— Catalyst for hydrosilylation reactions


FAQ

Q: Why does Ethyltrichlorosilane smoke when the container is opened?

A: The “smoke” is actually hydrogen chloride (HCl) gas, formed instantaneously when the liquid reacts with moisture in the air. Proper PPE and ventilation are mandatory.

Q: Is it safe to store this product in plastic containers?

A: No. ETCS should be stored in high-quality carbon steel or stainless steel drums. It can degrade many plastics and the resulting HCl gas can cause pressure buildup.

Q: How does the reactivity of Ethyltrichlorosilane compare to Methyltrichlorosilane?

A: It is slightly less volatile than Methyltrichlorosilane but shares a similar high level of reactivity towards hydrolysis and alcoholysis.

Q: Can Ethyltrichlorosilane be shipped by air?

A: It is strictly regulated as a Class 8 (Corrosive) and Class 3 (Flammable) material (UN 1196). Sea freight in UN-certified drums is the standard method.

Q: What is the shelf life of Ethyltrichlorosilane?

A: Typically 12 months, provided the seal remains intact and it is stored under nitrogen in a cool, dry place away from direct sunlight.

Technical Parameters

Parameter Value
Appearance Colorless Transparent Liquid
Assay (GC) ≥ 99.0%
Silicon Tetrachloride (SiCl4) ≤ 0.5%
Ethyldichlorosilane ≤ 0.3%
Density (d4/20) 1.235 - 1.245
Color (APHA) ≤ 30

Quick Information

EINECS 204-072-6
Molecular Weight 163.51 g/mol

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