2,2′-Azobis(2-methylpropionitrile)

CAS Number

78-67-1

Molecular Formula

C₈H₁₂N₄

Also known as:

AIBN; 2,2'-Azobis(2-methylpropionitrile); Azobisisobutyronitrile (common alternate name used in practice)

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Product Description

2,2′-Azobis(2-methylpropionitrile) AIBN CAS 78-67-1
AIBN is an azo-type organic compound supplied as a pale yellow to white crystalline powder. It thermally decomposes to generate stable carbon-centered radicals and nitrogen gas, providing a controllable radical source for free-radical polymerizations, crosslinking, graft polymerizations and laboratory radical chemistry. AIBN is processed under temperature-controlled, inert and moisture-restricted conditions to ensure safety and predictable initiation performance.

Applications

  • Free-radical polymerization initiator
    AIBN thermally generates radicals used to initiate bulk, solution, suspension and emulsion polymerizations of vinyl monomers where a predictable initiation temperature and radical flux are required.
  • Crosslinking and curing
    Used as a thermal radical source to cure or crosslink thermosets, elastomers and coatings at controlled temperatures, enabling tailored network formation.
  • Graft polymerization and surface modification
    Applied in grafting reactions to functionalize polymer backbones or surfaces (e.g., grafting polar monomers onto polyolefins) for adhesion, compatibilization or property tuning.
  • Laboratory reagent and R&D
    Common laboratory initiator for small-scale polymer synthesis, mechanistic studies and controlled radical reactions; used where AIBN’s decomposition profile and solubility fit the chemistry.

Technical Parameters

Parameter Value
Assay ≥ 98.0
Appearance Pale yellow to white crystalline powder
Moisture / Loss on drying (%) Moisture / Loss on drying (%)
Melting point (°C) 101–106
Residue on ignition (% w/w) ≤ 0.1

Applications

Curing Agents/Catalysts

Quick Information

EINECS 201-132-2
Molecular Weight 164.21 g/mol

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